Terahertz absorption spectroscopy plays a key role in physical, chemical and biological systems as a powerful tool to identify molecular species through their rotational spectrum fingerprint. Owing to the sub-nanometer scale of molecules, radiation-matter coupling is typically dominated by dipolar interaction. Here we show that multipolar rotational spectroscopy of molecules in proximity of localized graphene structures can be accessed through the extraordinary enhancement of their multipolar transitions provided by terahertz plasmons. In particular, specializing our calculations to homonuclear diatomic molecules, we demonstrate that a micron-sized graphene ring with a nano-hole at the core combines a strong near-field enhancement and an inherently pronounced field localization enabling the enhancement of the dipole-forbidden terahertz absorption cross-section of H+2H2+ by 8 orders of magnitude. Our results shed light on the strong potential offered by nano-structured graphene as a robust and electrically tunable platform for multipolar terahertz absorption spectroscopy at the nanoscale.
From optics to hydrodynamics, shock and rogue waves are widespread. Although they appear as distinct phenomena, new theories state that transitions between extreme waves are allowed. However, these have never been experimentally observed because of the lack of control strategies. We introduce a new concept of nonlinear wave topological control, based on the one-to-one correspondence between the number of wave packet oscillating phases and the genus of toroidal surfaces associated with the nonlinear Schrödinger equation solutions by the Riemann theta function. We prove it experimentally by reporting the first observation of supervised transitions between extreme waves with different genera, like the continuous transition from dispersive shock to rogue waves. Specifically, we use a parametric time-dependent nonlinearity to shape the asymptotic wave genus. We consider the box problem in a focusing Kerr-like photorefractive medium and tailor time-dependent propagation coefficients, as nonlinearity and dispersion, to explore each region in the state-diagram and include all the dynamic phases in the nonlinear wave propagation. Our result is the first example of the topological control of integrable nonlinear waves. This new technique casts light on dispersive shock waves and rogue wave generation and can be extended to other nonlinear phenomena, from classical to quantum ones. The outcome is not only important for fundamental studies and control of extreme nonlinear waves, but can be also applied to spatial beam shaping for microscopy, medicine, and spectroscopy, and to the broadband coherent light generation.
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