The First Experimental Observation of Ultrametricity

https://www.researchsquare.com/article/rs-5433512/v1

Ultrametricity is a fundamental mathematical concept that describes a particular metric space in which every triplet of points in the space forms an isosceles triangle. The ultrametric space differs from the usual Archimedean metric, where three points are allowed from any triangle.

Ultrametricity is the topology of hierarchical architectures. Examples can be found in taxonomy, where phylogenetic trees are ultrametric, mathematics with p-adic numbers, geography for measuring landscape complexity, and physics, where complex systems have intrinsically an ultrametric structure.

The Noble Prize Giorgio Parisi demonstrated this within the theory of spin glasses, where the overlap between spins exhibits ultrametricity, with the mathematical solution given by the full replica symmetry breaking.

An experimental demonstration of this is still lacking due to the difficulty of finding measurable physical observables.

In 2015, we introduced random lasers as photonic counterparts of spin glasses, and we demonstrated the replica symmetry breaking by directly measuring the overlap between spins, known as the order parameter in the description of glass phase transitions.

In the work, we clearly show the hierarchical organization of the overlap matrix reproducing the Parisi Ansatz, and we experimentally prove the ultrametric nature of the replica states.

For the first time, we measure the distance between any three replicas forming a triangle, and we report the growth of the distribution of isosceles tringles when the system enters the glassy regime. This is an unambiguous way to demonstrate ultrametricity and has been previously done only in numerical simulations.

In addition, from the hierarchical structure of the spin states, illustrated as dendrograms, and the distances between replicas, we attain the first topological energy landscape of a complex system from experiments.

The great potentiality of our research is the ability to access measurable spins from emission spectra and to quantify the overlap parameter. Random lasers are photonic spin glasses, as they manifest a clear phase transition from a paramagnetic ordered state to a glassy disordered one by increasing the system’s energy. Thanks to this powerful asset, we demonstrate the ultrametricity of the replica space. We report the experimental energy landscape with a topology that changes from a flat large basin to the coexistence of many metastable minima and the braking of ergodicity in the glassy state.

Biosensing with free space whispering gallery mode microlasers

Highly accurate biosensors for few or single molecule detection play a central role in numerous key fields, such as healthcare and environmental monitoring. In the last decade, laser biosensors have been investigated as proofs of concept, and several technologies have been proposed. We here propose a demonstration of polymeric whispering gallery microlasers as biosensors for detecting small amounts of proteins down to 400 pg. They have the advantage of working in free space without any need for waveguiding for input excitation or output signal detection. The photonic microsensors can be easily patterned on microscope slides and operate in air and solution. We estimate the limit of detection up to 148 nm/RIU for three different protein dispersions. In addition, the sensing ability of passive spherical resonators in the presence of dielectric nanoparticles that mimic proteins is described by massive ab initio numerical simulations.

https://doi.org/10.1364/PRJ.477139

Parisi Nobel lecture mentioning our experiments

This is the extended version of the Giorgio Parisi Nobel lecture mentioning our experiments in nonlinear optics and random laser with the first observation of Replica Symmetry Breaking

https://arxiv.org/abs/2304.00580

See also Coloquio at the University of Pernambuco on youtube

See also Observation of replica symmetry breaking in disordered nonlinear wave propagation

See also The Experimental Observation of Replica Symmetry Breaking in Random Lasers